Which configuration step is NOT standard when setting up a new purchasing organization in SAP S/4HANA?

When setting up a new purchasing organization in SAP S/4HANA, setting up payment terms for the purchasing organization is not a standard configuration step. The core focus during the initial setup of a purchasing organization typically involves configuring the structure and foundational elements necessary for procurement processes, which includes aspects like defining the purchasing organization parameters, selecting purchasing groups, and configuring vendor master data.

In contrast, while payment terms are certainly important in transaction processing and can be customized later, they are not a fundamental part of establishing the organizational structure itself. This means that payment terms can be adjusted as necessary based on the specific agreements with suppliers and do not need to be defined at the time of the purchasing organization setup. Such terms can be added or modified within specific purchasing documents or vendor transactions once the overall structure is in place.